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The present investigation deals with experimental and theoretical studies related to nucleate
pool boiling heat transfer of single component liquids and their binary and ternary mixtures
on a single horizontal plain as well as integral-fin tubes at atmospheric pressure with a
view to understand their boiling characteristics. The single component liquids investigated are
acetone, isopropanol and water. As regards the binary liquid mixtures, they include aqueous
mixtures namely; acetone-water and isopropanol-water and hydrocarbon mixtures of acetoneisopropanol,
whereas ternary liquid mixtures consisting of acetone, isopropanol and water.
In fact, the experimental data have been obtained for boiling of 22 binary and 12 ternary
compositions as well as their pure components on three horizontal heating tubes one by one.
One of the tubes is of plain surface and the remaining ones are of integral-fin surfaces
of 1mm height trapezoidal shape, but of different fin densities, of 748 and 1024 fpm. Each
heating tube has an axial hole of 18 mm diameter for its cartridge electric heater to supply
heat for boiling of liquid pool. The heated length of each tube is 108.0 mm, and the outer/
envelope diameter of plain/integral-fin tube is 31.2 mm.
The experimental set-up has been carefully designed, fabricated and commissioned to ensure
reliable and accurate experimental data. For this, surface area of the condenser, liquid pool height
over the heating tube, placement of wall and liquid thermocouples, deaeration oftest liquid, thermal
stabilization ofheating tube surface, homogeneity of heating surface, and various precautions during
experimentation have been the main considerations. The experimental data were obtained for heat
fluxes varying from 57,624 W/m2 to 10,391 W/m2, in decreasing order at atmospheric pressure.
While carrying out experiments with liquid mixtures, the composition of mixtures were determined
before and after a given experimental run. It was found that two values were almost the
same within ±0.01 mole fraction.
Analysis of experimental data shows that heat transfer coefficients of binary and ternary
liquid mixtures depend upon their compositions in addition to heat flux. The heat transfer
coefficients for boiling of single component liquids and also of their binary and ternary liquid
mixtures on plain tube get enhanced when the surface of tube is finned and the enhancement
is more pronounced when fin density is 1024 fpm as compared to 748 fpm.
Further, the data obtained and reported as part ofthis investigation provide valuable and unique information
about nucleate pool boiling heat transfer coefficients. Itis revealed that addition of acomponent
leads to degradation in boiling heat transfer coefficient of mixtures on plain as well as integral-fin
tubes, having approximately the similar trend. This degradation, expressed as degradation factor,
(h/h.d), happens to be a function of IY-XI for agiven binary/ternary liquid mixture, irrespective
of heating surface.
The heat transfer coefficient prediction accuracies of the existing correlations
have been evaluated by employing the earlier and present experimental data of liquid
mixtures boiling on plain tube. It is noted that correlation proposed by Schlunder (1982)
provides the best predictions of heat transfer coefficient, if the Stephan-Abdelsalam correlation
is employed to calculate ideal heat transfer coefficient, h.d. However, predictions due to Palen-
Small (1964) and Thome-Shakir (1987) are also reasonably well.
A new correlation for the prediction of nucleate pool boiling heat transfer coefficients
of binary mixtures on horizontal plain tube, based on the postulated mechanism of heat
and mass diffusion to growing vapour bubbles on heating surface, has been derived.
It is important to emphasize that this correlation is simple and convenient since it is free from
such empirical constants, whose determination, as is noted in available correlations, generally
involves a tedious exercise. Thus, this new correlation is unique. It is also important to underline
that this correlation accounts for the variation in physico-thermal properties ofthe mixtures through
die Stephan-Abdelsalam correlation which is employed to estimate ideal heat transfer
coefficient, hjd. The influence of the phase equilibrium on mixture boiling due to preferential
evaporation of the more volatile component is taken care of through the quantity known
as 'boiling range'. An excellent agreement is noted between experimental and predicted heat transfer
coefficients from the new correlation. For this, the experimental data of present and earlier
investigations available in open literature have been employed. Further, it is also established that the
derived correlation predicts better than the best of the existing correlations.
Another new correlation has also been derived for the boiling of mixtures on integral-fin tubes by
incorporating surface correction factor. This correlation also correlates reasonably well the
experimental data of the present investigation and those from open literature.
It is important to note that the derived correlations in the present investigation
can be successfully extended to predict boiling heat transfer coefficient of ternary liquid
mixtures with a good agreement between experimental and predicted values.
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