Abstract:
The present investigation deals with the theoretical studies
pertaining to concentration of weak kraft black liquor in
multiple effect evaporators in the pulp and paper mills for
recovery of chemicals with the distinct aim to make the
evaporation system achieve high gains in energy efficiency. Thus,
in essence, it is an attempt to provide short term measures to
conserve steam energy in the evaporator house of the mills
without incorporating any hardware which necessitates capital
input burden on the part of management. In other words, this
investigation considers the variations in input parameters, viz.,
the liquor feed temperature, liquor feed concentration, steam
temperature, temperature in the last effect, and, liquor feed
rate, to evaluate their influence on steam consumption, steam
economy along with heating surface area requirements. The effect
of choice of the liquor flow sequence has also been investigated
on steam energy requirements. Hence, it represents, to some
extent, a short term measure to solve the complicated issue of
energy requirements in black liquor evaporators.
Equations based on material- and energy- balances and heat
transfer rate have been formulated for this purpose. For
calculation of overall heat transfer coefficient, the
Gudmundson's model is employed. It is important to note that
these equations are of general nature and not necessarily
applicable to black liquor of any set of physico-thermal
properties.
The above equations are capable of computing quantities
like; boiling point rise, temperature and concentration of liquor
in each effect, steam consumption, steam economy, heating surface
area requirements, etc. of the evaporators having any number of
effects.
For the solution of these equations, Newton-Raphson method
has been employed. A set of computer programme in FORTRAN 77 has
been developed and executed using an IBM PC/AT 486 machine.
General applicability of the equations to solve for various
quantities has been supported by an excellent agreement between
the predicted quantities and the reported values of McDonald in
the available literature.
Sensitivity analysis has been performed to screen out
qualitatively the input parameters having appreciable effect on
the output parameters, viz.^ saturation temperature and
concentration of each effect, steam consumption, steam economy
and heating surface area of evaporators for improved design and
control strategies of multiple effect evaporators.
The investigation has categorized the liquor flow sequences
into two main groups, namely; backward-and mixed-feeds. As
regards the backward feed, it has been further classified into
sequences with and without split of liquor feed and steam. This
facilitates a systematic study of the effect of liquor flow
sequence on the steam consumption, steam economy and heating
surface area of evaporators.
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Finally, it may be mentioned that this investigation
suggests the use of sextuple effect evaporator with split of
liquor feed evenly among 5th and 6th effects and steam in the 1st
5
effect, leading to a sequence >4- 3- 2- IB- 1A. This
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provides the best steam economy, along with the smallest
heating surface area requirements for concentrating the weak
kraft black liquor from its concentration lying between 0.12 and
0.20 to a final liquor product concentration of 0.45. This
observation holds good practically for the entire range of each
operating parameter used in the mills, as given in Table 3.3
A comparison between the above sequence and the Scandinavian
sequence also suggests that the latter is inferior to the former
as regards the steam consumption, steam economy and requirement
of heating surface area.