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In the current era, the progress of electronic technology is directly coupled with the
advancement made in materials science. Magnetoelectric materials are the potential candidate
for several multifunctional devices such as magnetic random-access memory, switches, magnetic
sensors and tunable resonators. In these kinds of composites, the Magnetoelectric (ME) response
is a product tensor property, i.e., outcome of the mechanical interaction between the
magnetostrictive effect (magnetic/mechanical effect) occurring in the magnetic phase and the
piezoelectric effect (mechanical/electrical effect) present in the piezoelectric phase. The ME
coupling is observed in diverse structures such as bulk ceramic, two and three-phase ME
composites and nanostructured thin films. However, the ME composite thin films have attracted
enormous attention because different phases can be attached and designed at the atomic level
with higher precision and sharp interface. Furthermore, nanostructured thin film composites
enable the researchers to investigate the physical cause of the ME coupling effect at the nanoscale
level.
The strength of the ME coupling depends on many factors, such as interface quality, high
anisotropy magnetostriction, lattice mismatching, and functional characteristics of the individual
piezoelectric and magnetostrictive layers. The ideal candidates for magnetostrictive and
piezoelectric layers are ferromagnetic shape memory alloys (like-NiMnIn, NiMnSb, etc.) and
AlN, respectively. Ferromagnetic shape memory alloys (FSMAs) exhibit a large applied
magnetic field and temperature induced strain in the temperature region during the martensite to
austenite phase transition as compared to leading magnetostrictive materials such as Trefnol-D
and metglas. The NiMnIn exhibits giant magnetostriction coefficient at room temperature with
multiple degrees of freedom to tune its magnetostriction, i.e., by varying temperature, magnetic
field, stress. On the other hand, Aluminium Nitride (AlN) is a lead-free complementary metaloxide-
semiconductor (CMOS) compatible piezoelectric material with a high value of voltage
piezoelectric coefficient (e33). The deposition process of AlN is also well reproducible, and its
chemical compatibility is well suited with semiconductor fabrication technology. For strong
coupling between ferromagnetic and piezoelectric layers in the artificial magnetoelectric
heterostructure, it is desirable to fabricate high-quality thin films with a sharp interface that can
be attained by several growth techniques such as molecular beam epitaxy, pulsed laser
deposition, metal oxide chemical vapor deposition, sputtering. |
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