Please use this identifier to cite or link to this item: http://localhost:8081/xmlui/handle/123456789/12819
Title: SYNTHESIS AND ANALYTICAL STUDIES ON METAL COMPLEXES FOR C-H BOND ACTIVATION
Authors: Agarwal, Shilpi
Keywords: CHEMISTRY;METAL COMPLEXES;C-H BOND ACTIVATION;UV-VISIBLE
Issue Date: 2008
Abstract: The reaction of iron (II) chloride with 3,5-diisopropylpyrazole resulted in the formation of [(3,5-Pr12pzH)2FeC12]. The same reaction mixture in presence of different para substituted benzoate (p-X-OBz) and excess amount of H202 gave mononuclear Fe(III) complex [Fe(3-OCMe2,5-Pr'2pz)3].2X-OBz (where X = H, Cl, F, CH3, OCH3, CHO, CN, NH2, NO2). In these complexes one of the methine groups present in each of three 3,5-diisopropylpyrazole rings were oxidized during • oxidation and coordinated to iron centre. These complexes were characterized by elemental analysis, IR, UV-Visible and thermal studies
URI: http://hdl.handle.net/123456789/12819
Other Identifiers: M.Tech
Research Supervisor/ Guide: Singh, U. P.
metadata.dc.type: M.Tech Dessertation
Appears in Collections:MASTERS' DISSERTATIONS (Chemical Engg)

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